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Jetzt kostenlos anmeldenWay back in the 1970s, two chemists began studying the impact of certain molecules in the Earth's atmosphere. They found that these molecules might be the cause of Ozone breakdown. Ozone (O3) is a highly oxidising molecule. At ground level, ozone is a respiratory hazard. But thousands of metres above the Earth, in the stratosphere, it keeps everyone safe. These scientists paved the way for us to gain understanding and ultimately protect the ozone layer.
The Ozone Layer is a stratospheric shield of ozone in the stratosphere that protects humans and the environment from harmful levels of ultraviolet radiation from the sun.
On 15th September 1987, the Montreal Protocol on Substances that Deplete the Ozone Layer was signed. This groundbreaking global treaty was the first to address an environmental problem that was still theoretical. Furthermore, it is the only UN treaty to date that has been ratified by all 198 member states.
In 2014 it was set out that HCFCs would hopefully be completely phased out in developed countries by 2030 and developing countries by 2040.
The Montreal Protocol set out plans to regulate the production and consumption of ODS.
ODS (ozone-depleting substances) are man-made chemicals that damage the ozone layer when released into The Atmosphere.
The treaty phased out ODS consumption and production in a step-wise manner.
All parties had specific responsibilities, including:
All nations had equal responsibilities, but the timeline of change was based on their level of development.
In the early 1970s, a scientists realised that anthropogenic emissions of CFCs could damage the ozone layer.
CFCs (chlorofluorocarbons) are non-flammable, non-toxic chemicals. These non-harmful properties meant that they were commonly used as refrigerants, aerosol propellants and solvents.
However, once in the stratosphere, they can cause problems. The carbon-chlorine bonds break apart, creating chlorine free radicals that destroy ozone. Once released, these substances stay in The Atmosphere for many years.
Free radicals are unstable atoms (i.e. without a full outer shell of electrons). They react quickly with other atoms. In humans, they can damage cells, causing illness and ageing.
Without the work of Paul Crutzen and the Montreal Protocol, the ozone layer would likely have been destroyed, providing no protection from the sun's ultraviolet rays. This could destroy the environment - killing marine life and plants. Without crops, humans would have suffered famines, as well as diseases such as cataracts, skin cancer and immune system problems.
How are CFCs destroyed to prevent them from being released into the atmosphere?
The Montreal Protocol is considered highly successful. Without the Protocol, the ozone layer would be much more depleted than it is today.
The Montreal Protocol established the conversion to affordable, available substitutes for ODS.
Describing this treaty as a failure is difficult - but it was not without drawbacks.
Some criticised the treaty for bowing too much to industry influence. Others pointed out that the phasing-out of ODS led to a thriving black market and uncertainties in phaseouts of developing countries.
However, the most obvious drawback is encouraging the production of HFCs as an alternative product to CFCs.
HFCs (hydrofluorocarbons) are similar chemicals to CFCs but lack chlorine atoms. Thus, they do not produce free radicals that damage the ozone layer.
HFC-134a was the primary recommended alternative to the CFC-12 refrigerant.
HFCs were later discovered to be potent Greenhouse Gases.
On 15th October 2016, 197 countries signed the Kigali Amendment under the Montreal Protocol.
This amendment committed to cutting down on the production and consumption of HFCs by over 80% in the following 30 years - equivalent to 80 billion tons of CO2. Developed countries will reduce HFC consumption at the start of 2019. Most developing countries will end consumption in 2024, with a small number ending in 2028. Financing is provided to certain countries to help them transition to climate-friendly alternatives. The Kigali Amendment promoted enforcement, accountability and broad participation.
The Kyoto Protocol was adopted on 11th December 1997 - but due to a complex ratification process, it didn't enter into force until 16th February 2005. 192 parties signed the treaty - less than the Montreal Protocol.
The Kyoto Protocol set binding emission reduction targets for industrialised countries, economies in transition, and the European Union.
These targets required:
These targets add up to an average 5% emission reduction compared to 1990 levels.
The Montreal Protocol is considered much more successful than the Kyoto Protocol.
Hopefully you are now more aware of the Montreal Protocol, CFCs and HCFs as well as other protocols that have come into play since.
1. American Carbon Registry, Destruction of Ozone Depleting Substances, 2022
2. Cass Sunstein, Montreal versus Kyoto: A Tale of Two Protocols, University of Chicago Law School, 2006
3. Debra Wilson, How do free radicals affect the body?, 2017
4. Elizabeth DeSombre, The Experience of the Montreal Protocol: Particularly Remarkable, and Remarkably Particular, UCLA Journal of Environmental Law and Policy, 2000
5. Frederike Albrecht, Healing the Ozone Layer, 2019
6. Guus Velders, The importance of the Montreal Protocol in protecting climate, Environmental Sciences, 2007
7. Jim Clark, Uses of Halogenalkanes, 2015
8. Jos Lelieveld, Paul J. Crutzen (1933-2021), 2021
9. Lindsay Maizland, Global Climate Agreements: Successes and Failures, 2021
10. Lizzy Rosenberg, Here’s What Will Happen to Life on Earth, if the Ozone Layer Fully Depletes, 2021
11. Professor Thomas Peter, The Montreal Protocol at 30: what has it achieved?, 2017
12. United Nations Climate Change, What is the Kyoto Protocol?, 2022
13. United Nations Environment Programme, About Montreal Protocol, 2022
14. United States Environmental Protection Agency, Recent International Developments under the Montreal Protocol, 2021
Flashcards in Montreal Protocol15
Start learningWhat is the ozone layer?
The Ozone Layer is a stratospheric shield of ozone in the stratosphere that protects humans and the environment from harmful levels of ultraviolet radiation from the sun.
How many countries signed the Montreal Protocol?
The Montreal Protocol was signed by 198 states.
What are ozone-depleting substances?
Ozone-depleting substances are man-made chemicals that damage the ozone layer when released into the atmosphere.
What are CFCs?
CFCs (chlorofluorocarbons) are non-flammable, non-toxic chemicals. When they are in the stratosphere they release chlorine free radicals that destroy ozone.
What are free radicals?
Free radicals are unstable atoms (i.e. without a full outer shell of electrons). They react quickly with other atoms.
Who realised that CFCs had the potential to damage the ozone?
Paul Crutzen
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